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A transformation of spiro[4.4]nonatrienes to aryl-substituted, enantioenriched annulated fulvenes is reported. DFT calculations and empirical results support a novel mechanism of reaction involving a 1,5-vinyl shift from a vinyl–palladium species. 

Poisson's ratio in chiral Cosserat elastic solids is considered. Chirality allows the Poisson's ratio to exceed classical bounds, even if the material is directionally isotropic and all elastic moduli are within thermodynamic limits based on strain energy density. Poisson's ratio in chiral rods depends on the chiral elastic constants as well as on the shear and bulk moduli, assumed positive. Poisson's ratio can be greater than 0.5 or smaller than −1 for slender chiral specimens. 

The 3D‐printed titanium alloy Ti5553 solid and octet truss lattice specimens are studied via resonant ultrasound spectroscopy, free decay of vibration and quasi‐static methods to determine viscoelastic damping. Damping in solid alloy and a lattice is between 10⁻⁴and10⁻³. Much of the damping at high sonic frequency is attributed to stress‐induced heat flow between heterogeneities due to 3D printing. Pulsed wave ultrasound experiments disclose reverberation in the cell structure of the lattice. Continuous wave ultrasound experiments show that the transmissibility in the lattice rolls off beginning at about 50 kHz and becomes negligible above 110 kHz. By contrast, the polymer polymethyl methacrylate (PMMA), though it is viscoelastic, readily transmits waves up to 1 MHz. The cutoff frequency in the lattice is associated with the structure size, not intrinsic damping in the alloy. The octet truss lattice, in addition to providing good mechanical performance, is also an ultrasonic metamaterial.